diff --git a/xarray/core/datatree.py b/xarray/core/datatree.py
index 63066ff3fda..224c6e4c1ba 100644
--- a/xarray/core/datatree.py
+++ b/xarray/core/datatree.py
@@ -1046,6 +1046,7 @@ def drop_nodes(
     def from_dict(
         cls,
         d: Mapping[str, Dataset | DataTree | None],
+        /,
         name: str | None = None,
     ) -> DataTree:
         """
diff --git a/xarray/tests/test_datatree.py b/xarray/tests/test_datatree.py
index 1c47726b470..3368dd1f19b 100644
--- a/xarray/tests/test_datatree.py
+++ b/xarray/tests/test_datatree.py
@@ -1072,7 +1072,7 @@ def test_match(self):
 
     def test_filter(self):
         simpsons = DataTree.from_dict(
-            d={
+            {
                 "/": xr.Dataset({"age": 83}),
                 "/Herbert": xr.Dataset({"age": 40}),
                 "/Homer": xr.Dataset({"age": 39}),
@@ -1083,7 +1083,7 @@ def test_filter(self):
             name="Abe",
         )
         expected = DataTree.from_dict(
-            d={
+            {
                 "/": xr.Dataset({"age": 83}),
                 "/Herbert": xr.Dataset({"age": 40}),
                 "/Homer": xr.Dataset({"age": 39}),
diff --git a/xarray/tests/test_datatree_mapping.py b/xarray/tests/test_datatree_mapping.py
index 62fada4ab4f..1d2595cd013 100644
--- a/xarray/tests/test_datatree_mapping.py
+++ b/xarray/tests/test_datatree_mapping.py
@@ -19,8 +19,8 @@ def test_not_a_tree(self):
             check_isomorphic("s", 1)  # type: ignore[arg-type]
 
     def test_different_widths(self):
-        dt1 = DataTree.from_dict(d={"a": empty})
-        dt2 = DataTree.from_dict(d={"b": empty, "c": empty})
+        dt1 = DataTree.from_dict({"a": empty})
+        dt2 = DataTree.from_dict({"b": empty, "c": empty})
         expected_err_str = (
             "Number of children on node '/' of the left object: 1\n"
             "Number of children on node '/' of the right object: 2"
@@ -320,7 +320,7 @@ def weighted_mean(ds):
 
     def test_alter_inplace_forbidden(self):
         simpsons = DataTree.from_dict(
-            d={
+            {
                 "/": xr.Dataset({"age": 83}),
                 "/Herbert": xr.Dataset({"age": 40}),
                 "/Homer": xr.Dataset({"age": 39}),